[N,N′-Bis(4-bromobenzylidene)-2,2-dimethylpropane-κ2 N,N′]iodidocopper(I)
نویسندگان
چکیده
The title compound, [CuI(C(19)H(20)Br(2)N(2))], lies across a crystallographic mirror plane. The coordination around the copper centre is distorted trigonal planar, with a bite angle of 94.7 (3)°. A six-membered chelate ring in a chair conformation is formed by the coordination of the imine N atoms of the bidentate ligand to the Cu(I) atom. This conformation is required by the crystallographic mirror symmetry. The inter-planar angle between the benzene rings is 74.85 (19)°. The crystal structure exhibits weak inter-molecular C-H⋯π inter-actions, which link the mol-ecules into chains along the b axis.
منابع مشابه
[N,N′-Bis(4-bromobenzylidene)-2,2-dimethylpropane-κ2 N,N′]iodidocopper(I). Corrigendum
The chemical name of the title compound in the paper by Kia, Fun & Kargar [Acta Cryst. (2009), E65, m289] is corrected.[This corrects the article DOI: 10.1107/S1600536809005078.].
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